A "dinglespeed" is most advisable: no need to readjust brakes because the chain length remains the same, and you get straight chainline with either gear. So it's WI Dos in the rear and two chainrings in the front.
With a cassette rear hub it's easier: just buy two cogs of preferred size and put them on. I have my Moonlander setup like this: 33/21 for off-road use, 36/18 for commuting to and from trails.
If you only plan to change one gear and don't mind having the chainline off a bit, you could keep your current freewheel and buy another chainring to bolt on your spider. It'll be cheaper than the Dos freewheel - and your setup will be half-ready for the Dos freewheel if you get one after all.
Agree with all that is said above. I run a dinglespeed on my road Single-speed 16/19 rear with a 45/48 front.
I would prefer to go with a wide-base CK cogs + cassette for MTB as White only has two DOS-ENO sizes and I think they dropped their 3-tooth gap. It appears they only have 16/18 and 17/19 nowdays. I have their older 16/19 set which I think gives a much better spread. Also with cassette, you have chain line flexibility up the wazoo which is nice.
That said, I have been running my DOS on my road bike for probably 5 years and its great. Chain length does stay the same as long as you keep your tooth count spread the same front and rear. If you run rim-brakes its just different enough that you have to adjust your brake pads to be perfect. You Don't want a 1x2. Adjusting your brake may not sound like work now, but its annoying in the end.
In use over the last 5 years, I will say my 16T has 99% of actual use and the 19T gets used when climbing hills....
Its a neat concept to keep a clean drive train with the no-tensioner look, but in practice, seriously,.... 99% of the time I am only in one gear. I spent $100's on different spreads of 135 BCD (I run campy on that bike) chainrings.... so I had 45,46,48,49,50,51t rings so I could have some flexibility if I needed to..... I just sold all my spare rings except my 48T.... Perhaps I am lazy, but once the novelty of the dinglespeed wears off, I basically ended up just buying a geared bike when I need gears. (I have 1 geared and 1 single speed for both road and MTB bikes)
On my SS Rigid MTB, I look like a moron spinning on the road to the trail,.... but like being able to hop onto the trail and not fiddle with my bike just to get me "trail ready"
I can post pics of the Dinglespeed if that helps you and clears anything up... I still use the bike quite a bit, but between 5 bikes, "quite a bit" is all relative.