Kroil works VERY well. The only product that works better in short burst of time is 50/50 acetone/atf (which you need to shake, and will eventually separate...even once you've applied it).
I had an unloved garbage-picked frame [steel] with a stuck seatpost/bottom bracket [aluminum parts]. The seatpost was not budging, so I hit it with Kroil, and left it for a week. When I came back, a minute of twisting/hammering on the bottom of the seatpost, and it was out. Likewise, the bottom bracket; I barely moved the cartridge, then sprayed the joint with Kroil. You can literally see it bubble/wick into the gap. Afterwards, a few minutes with the breaker bar, and it was out.
That said, temper your expectations. Aluminum corrosion is a 'B', and you can't really work with heat, since CF composite is largely temperature stable. You might try a product called "Freeze Off" (you can get it at the auto parts store--sold by CRC) shot in through the bottom bracket shell. The cold caused by the chemical reaction could shrink the aluminum post, break some corrosion, and allow it to wick up to the seatpost clamp.