Alivio is pretty nice. I like it better than Acera.
On my bike, I've generally chosen SLX/LX, although as long as I keep ripping them off before I wear them out, I've just been doing Deore rear derailleurs. However, I'm fully aware that what I'm getting in spending a bit more on SLX and LX is some refinement. The basic reliability and function are already there with Alivio, IME. Acera, I'm a bit less positive on. Not that this stuff can't be made to work, but I feel like it doesn't cope as well with dirt, less-than-ideal shifting technique, etc.
SRAM hooked me up when I needed some help last year, but I have to say, I still like Shimano better. I prefer the smoother shifting and there's a little tab on a Shimano rear derailleur that I think makes them function more robustly when I shift a few gears at a time.
Wheels are a tough one. I actually don't mind Shimano's cup and cone hubs, although I think almost everyone else who's doing that technology is doing it really cheaply, in a way that detracts from the longevity of the hub. But I haven't had any revelations about POE, don't tend to destroy my hubs, can rebuild a hub, etc. etc. So I seem not to benefit much from a fancier one, and with a modicum of care, Shimano hubs last a good, long time. I take back not destroying hubs - I did kill a Formula cup and cone hub that didn't have seals. It went down easy.

My mountain bike currently has DT hubs, 370s I think. An OEM hub, anyway. They're fine.
Forks are another tough one. As far as I'm concerned, if I can't adjust the spring rate and the rebound damping for me, I'd rather have a rigid fork. That rules out a ton of OEM forks, but forks sell bikes. People also buy jacked up SUVs and drive them to work. RockShox, Marzocchi, Fox and Manitou are common brands of "real" fork in the US. There are a couple of other nice brands too, just less common. Supposedly, Suntour makes some real forks but the OEM ones are cheaper than I was willing to go last time I killed a fork - if my friend hadn't offered me his old Marzocchi at a good price, I'd probably have gone rigid. It's also good to have metal internals - for RS, that means the Motion Control damper or better - available service parts - that tends to be RS, Marz and Fox, the Manitou is supposed to have their moments - and compression dampers are pretty cool. IMHO, lockouts are a stupid solution for a problem better solved another way.
Brakes - if I can't have major-brand Hydraulics, Avid BB5s and BB7s are okay, and V-brakes didn't magically quit working when discs came out. I'm suspicious of off-brand hydraulics and I'd just as soon not have someone else's mechanical disc brakes.
What else? Retail doesn't get good until somewhere around $1200, IMO. Sometimes there are other factors at work to back one into it anyway.