It's hard to answer your question without more info. What kind of riding do you do? What size is the frame? What size are you? What travel fork are you running? How does the bike handle now? Also, why do you feel the need for a layback post/longer stem? It sounds to me like you are trying to make the best out of a frame that may be too small.
My experience may help. My main bike is down with pivot issues, so I pulled out my backup bike - a large Chameleon with 100mm stem, 4" travel Fox Float, and straight up Thompson post. The bike has basically been unused since I built it up, so it wasn't really dialed in. My first ride on the local tight twisty trails I felt like I couldn't get the front wheel to carve; the head angle felt too slack, and I couldn't dive into the corners like i wanted. I adjusted my seat forward, to get more weight over the front tire, which gave me more traction as well as more sag and a steeper effective head angle. Another welcome benefit of moving my seat forward was that my a$$ was no longer getting hammered as hard by the ultra stiff Chameleon rear triangle.
My point in all this is not that my situation is exactly the same as yours, but that when you start making drastic changes to your riding position, you are going to run into some interrelated handling issues. I personally think that a layback post is a band-aid that will have a negative effect on handling for xc or all mountain use, especially on a bike with a tight rear triangle like the Chameleon. If you need to stretch out I'd run your seat as far back as you can get it on the post you have and go for a 100mm stem.