Different brake brands have pads with different surface areas. Looks like you're using your old Tektro rotors with the new Shimano calipers. I wouldn't expect the braking tracks to line up exactly.
As long as the pads are not overhanging the outer edge of the rotor, you'll be fine. If they are, then that's a problem. The angle on your front caliper picture makes it hard to tell, but it looks like the rear caliper probably is not overhanging.
As long as the pads are not overhanging the outer edge of the rotor, you'll be fine. If they are, then that's a problem. The angle on your front caliper picture makes it hard to tell, but it looks like the rear caliper probably is not overhanging.